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Turning Agricultural Waste into a Powerful Solution: Enhanced Lead Removal via Chemically Modified Oat Straw

By
Jelena Dimitrijević Orcid logo ,
Jelena Dimitrijević
Contact Jelena Dimitrijević

Institute for Technology of Nuclear and Other Mineral Raw Materials, 86 Franchet d’Esperey St. , 11 000 Belgrade , Serbia

Sanja Jevtić Orcid logo ,
Sanja Jevtić

Faculty of Technology and Metallurgy, University of Belgrade, 4 Carnegie , 11 000 Belgrade , Serbia

Marija Simić Orcid logo ,
Marija Simić

Institute for Technology of Nuclear and Other Mineral Raw Materials, 86 Franchet d’Esperey St. , 11 000 Belgrade , Serbia

Marija Koprivica Orcid logo ,
Marija Koprivica

Institute for Technology of Nuclear and Other Mineral Raw Materials, 86 Franchet d’Esperey St. , 11 000 Belgrade , Serbia

Aleksandar Jovanović Orcid logo ,
Aleksandar Jovanović

Institute for Technology of Nuclear and Other Mineral Raw Materials, 86 Franchet d’Esperey St. , 11 000 Belgrade , Serbia

Milica Mišić Orcid logo ,
Milica Mišić

Institute for Technology of Nuclear and Other Mineral Raw Materials, 86 Franchet d’Esperey St. , 11 000 Belgrade , Serbia

Jelena Petrović Orcid logo
Jelena Petrović

Institute for Technology of Nuclear and Other Mineral Raw Materials, 86 Franchet d’Esperey St. , 11 000 Belgrade , Serbia

Abstract

The release of industrial effluents and agricultural runoff containing heavy metals, like lead (Pb), poses serious environmental risks. This study explores the adsorption capacity of potassium hydroxide (KOH)-modified oat straw (KOS) as an effective, low-cost biosorbent for lead removal from contaminated water. The modification process increased the surface area and improved the availability of functional groups, enhancing adsorption performance compared to unmodified oat straw. Structural analysis was conducted using SEM and FTIR. Batch experiments evaluated the effects of contact time, initial Pb²⁺ concentration, and pH on lead removal efficiency. The adsorption process followed pseudo-second-order kinetics, with chemisorption as the main mechanism. Isotherm studies indicated that the Langmuir and Redlich-Peterson models offered the best fit, showing a maximum adsorption capacity of 191.41 mg/g. These findings highlight the potential of KOH-modified oat straw as a sustainable solution for heavy metal removal from wastewater, effectively valorizing waste biomass.

Citation

This is an open access article distributed under the Creative Commons Attribution License which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly cited. 

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